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Surfactants And Oil-Based Adjuvants In Agricultural Applications (Technical Insights)

Published by: Frost & Sullivan

Published: Feb. 1, 2001


Table of Contents


Executive Summary




Objectives of Study




Scope of Study




1. Introduction




2. Agricultural Chemicals And Formulations

2.1 Introduction

2.2 Pesticidal Active Ingredients

2.3 Pesticide Formulations

2.3.1 General Formulation Guidelines

2.3.2 International Formulation Codes

2.3.3 Formulation Types

2.3.3.1 Solution Concentrates

2.3.3.2 Emulsifiable Concentrates

2.3.3.3 Wettable Powders

2.3.3.4 Suspension Concentrates

2.3.3.5 Water-Dispersible Granules

2.3.3.6 Controlled Release Formulations

2.3.3.7 Seed Treatments

2.3.3.8 Other Formulation Types

2.3.3.9 Built-In Wetter Formulations




3. Surfactant Adjuvants And Properties

3.1 Introduction

3.2 Types of Surfactants

3.2.1 Anionic Surfactants

3.2.2 Cationic Surfactants

3.2.3 Nonionic Surfactants

3.2.4 Amphoteric Surfactants

3.3 Properties of Surfactants

3.3.1 Adsorption/Surface Tension

3.3.2 Micellization/Solubilization

3.3.3 Krafft Temperature and Cloud Points

3.3.4 Wetting and Contact Angles

3.4 Surfactant Products

3.4.1 Anionic Surfactants

3.4.2 Nonionic Surfactants

3.4.3 Cationic Surfactants

3.4.4 Amphoteric Surfactants




4. Oil-Based And Surfactant-Based Adjuvants

4.1 General Introduction

4.2 Spray Oils

4.2.1 Mineral Oil-Based Adjuvants

4.2.2 Vegetable Oil-Based Adjuvants

4.3 Surfactant-Based Adjuvants




5. Other Spray Tank Adjuvants

5.1 Introduction

5.2 Spray Drift Control

5.3 Stickers

5.4 Defoamers

5.5 Compatibility Agents

5.6 Miscellaneous Adjuvants




6. Mode Of Action Of Adjuvants In Spray Applications

6.1 Introduction

6.2 Atomization

6.3 Transport to Target

6.4 Droplet Impaction

6.5 Wetting and Spreading

6.6 Drying of Droplets and Deposit Effects

6.7 Uptake and Translocation

6.8 Biological Effect

6.9 Spray Tank Problems

6.10 Major Objectives of Adjuvant Usage




7. Application Techniques For Agrochemicals

7.1 Historical Development

7.2 Conventional Sprayers

7.2.1 Portable Sprayers

7.2.2 Tractor-Powered Sprayers

7.2.3 Aerial Sprayers

7.3 Controlled Droplet Application

7.4 Electrically Charged Droplets

7.5 Global Positioning System

7.6 Closed Transfer Systems

7.7 Seed Treatment Applications




8. Market Trends For Formulations And Adjuvants

8.1 World Market for Agricultural Formulations

8.2 Western European Market for Agricultural Formulations

8.3 Generic Agrochemicals Market

8.4 World Market for Surfactants in Formulations and Adjuvants

8.4.1 Global Surfactants and Adjuvants Market

8.4.2 Western European Surfactants and Adjuvants Market

8.4.3 North American Surfactants and Adjuvants Market

8.4.4 Japanese Surfactants and Adjuvants Market

8.4.5 Surfactants for Formulations and Adjuvants

8.5 Market for Oil-Based Adjuvants in N. America, W. Europe, and Japan




9. Future Trends In Formulations And Adjuvants

9.1 Introduction

9.2 Formulation Developments

9.2.1 Water-Dispersible Granules

9.2.2 Suspension Concentrates

9.2.3 Suspoemulsions

9.2.4 Emulsions

9.2.5 Microemulsions

9.2.6 Controlled Release Formulations

9.2.7 Other Formulation Trends

9.2.8 Built-In Wetter Formulations

9.2.9 Biotechnology

9.3 Adjuvant Developments

9.3.1 Silicone-Based Surfactants

9.3.2 Diols

9.3.3 N-Alkyl Pyrrolidones

9.3.4 Alkyl Polysaccharides

9.3.5 Alkenyl Succinic Anhydride Condensates

9.3.6 Methylated Vegetable Oils

9.3.7 Phospholipids

9.3.8 Liquid Crystals

9.3.9 Urea Clathrates

9.3.10 Future Trends




10. Developments In Regulatory Requirements

10.1 US Regulatory Requirements

10.2 Regulatory Requirements in Western Europe

10.3 Status of Alkylphenol Ethoxylates in Pesticide Products




Appendix I: Typical Selected Formulations

1. Wettable Powders

2. Emulsifiable Concentrates

3. Suspension Concentrates

4. Water-Dispersible Granules




Appendix II: Main Suppliers Of Surfactants And Oil-Based Adjuvants




Appendix III: Information Resources




Tables (Sampling Of )

8.19 North American Surfactant Consumption by Application (1990-2005) (1000 mt)

8.20 Japan Surfactant Consumption by Type (1990-2005) US$ Millions

8.21 Japan Surfactant Consumption by Type (1990-2005) (1000 mt)

8.22 Japan Surfactant Consumption by Application (1990-2005) US$ Millions

8.23 Japan Surfactant Consumption by Application (1990-2005) (1000 mt)

8.24 Surfactants Used in Formulations and Adjuvants by Region in 1998

8.25 Surfactants for Agrochemical Formulations by Region (1998)

8.26 Global Usage of Surfactants in Formulations by Surfactant Type in 1998

8.27 Surfactant Usage by Formulation Type in Western Europe in 1998

8.28 Surfactants Used for Adjuvants by Region (1998)

8.29 Breakdown of Surfactant Usage for Adjuvants in N. America, W. Europe, and Japan (1998)

8.30 Usage of Oils for Adjuvants by Global Region (1998)

9.1 Typical Surfactants for Suspoemulsion Formulations




Figures (Sampling Of)

2.1 Structure of Surfactants Used in EC Formulations

3.1 Spray Application and Effect of Adjuvants

4.1 Structure of Triacylglycerol Oils

6.1 Formation Between Droplets from a Spray Nozzle

6.4 Diagram Showing Poor and Good Wetting

9.1 Typical Structure of a Silicone Surfactant and a Tallowamine Ethoxylate

Abstract

Stay on Top of the Latest Developments in the Dynamic Field of Agricultural Formulated Products

This new Report from Hewin International gives you unprecedented insight into this $420 million-and-growing field. With the introduction of genetically modified crops, companies have been motivated to develop safer and more convenient surfactant product formulations. Furthermore, due to global consolidation of the agrochemical industry and mounting environmental concerns, regulatory pressures on the use of pesticides and additives have increased dramatically. Keeping abreast of the market trends will strengthen your company's position to take advantage of growing investment, licensing, joint venture, and partnering opportunities. You'll be privy to an in-depth examination of:

  • Current and future market trends for agricultural product formulations, surfactants, and oil-based adjuvants to the year 2005. We evaluate world markets by global regions—the established markets of North America, Western Europe and Japan, and the growing markets of Eastern Europe, Latin America and the Asian Pacific.
  • The use of built-in surfactant wetter to enhance biological efficiency.
  • All major surfactant types and their properties. Modes of action to enhance the biological activity of agrochemicals by surfactants.
  • Oil-based adjuvants and other materials added to spray tanks to improve the effectiveness of agricultural products.
  • The use of other spray tank additives to improve biological efficacy and reduce pesticide product wastage.

A successful R&D strategy begins with this report's invaluable analysis of:

  • Trends toward safer and more convenient product formulations and requirements for more environmentally safe adjuvants with lower toxicity profiles.
  • Effective marketing strategies that take into account legislative and regulatory developments.
  • Opportunities for new types of product formulations, surfactants and oil-based adjuvants.
  • Commercial requirements for improved agricultural spraying techniques, including ultra-low volume spraying, controlled droplet application, charged droplet application, and global positioning systems.

Cost effective and comprehensive

Surfactants and Oil-Based Adjuvants is a unique market study based on primary research and interviews with industry leaders at more than 50 major companies, universities, and government funded research facilities. The result is the most cost effective, concise source of information available on this burgeoning market. Bayer, BASF, DuPont (UK) Ltd., Novartis, Monsanto, and Hoechst Schering AgrEvo GmbH. are among those highlighted. Complete contact informa-tion is provided to assist you in pursuing business opportunities and partners.

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